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Preheat the oven to 325°F. Spray two 9-inch round cake pans with non-stick cooking spray (or use the wrappers from the butter to grease them thoroughly).
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In one mixing bowl, combine the white cake ingredients: cake mix, butter, eggs, sour cream, buttermilk and vanilla extract. Beat on low speed for 1 minute and then on medium-high speed for two additional minutes. Set aside.
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In a second mixing bowl, combine the chocolate cake ingredients: chocolate cake mix, butter, eggs, sour cream, buttermilk and vanilla extract. Beat on low speed for 1 minute and then on medium-high speed for two additional minutes.
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Using an ice cream scoop or large spoon, pile dollops of cake batter into the pans, rotating between the white and chocolate cake mixes. Fill the pans about ⅔ of the way full to prevent overflowing - you may not use all of the batter.
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Use a knife to cut through the batter and swirl the two colors. Do not over swirl which can result in the colors blending.
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Bake for about 40 minutes or until a toothpick inserted into the cakes comes out with just a few crumbs (the pans are going to be more full than with a single cake mix, so the cook time will likely be 5-10 minutes longer than indicated on the box of cake mix.
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Cool the cakes for 10-15 minutes and then remove the cakes from the pans and let them cool completely on a cooling rack.
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Meanwhile, prepare the frosting: Chop the German chocolate baking bar into small pieces. Use a double boiler or 30-second increments in the microwave to melt the chocolate. Stir until fully melted and set aside to cool.
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Use a whisk to stir together the cocoa powder and hot water (or hot cream) until smooth and shiny.
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In a large mixing bowl, beat together the softened butter, cooled German chocolate, cocoa powder mixture, and powdered sugar. Beat until fully combined and fluffy.
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Level the tops of the cakes (and any lip from overfilled cake pans) with a serrated knife.
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Frost the bottom cake layer with about ½ cup of chocolate frosting. Stack the second cake layer on top of the first, top side down. Frost the top and sides of the cake with the remaining frosting.